Revision: Atoms and Molecules
1) Atomic structure - To determine the number of protons, neutrons and elections in an atom, use the Periodic Table to find the chemical symbol. Then check out the nucleon/mass number and the proton/atomic number.
- First shell of atoms can only hold two electrons and the rest can hold a maximum of eight.
- The way the electrons are arranged in an atom is known as the electronic configuration.
- eg: Chlorine atom has an electronic configuration of 2,8,7.
- The shell that is furthest away from the neucleus is called the outer shell or the valence shell.
- The Electons found in this shell are called valence electrons.
- The chemical properties of an element depends on the number of valence electrons.
- This is why elements with the same number of valence electrons( e.g. Gp 1 sodium and potassium) have similar chemical properties.
- Group numbers show how many valence electrons an atom of each element has.
- Period numbers show how many electron shells an atom of each element has
- E.g. an atom of nitrogen found in Group 5, Period 2 will have 2 electron shells and 5 valence electrons.
- Atom: Smallest particle of an element
- Molecule: Two or more atoms chemically combined together.
- Molecules of Elements: Two or more atoms of the same element chemically combined together. E.g. Oxygen, ozone, nitrogen, hydrogen, phosporys.
- Molecules of Compunds: Two or more atoms of different elements chemically combined together. E.g. water, sulphur dioxide, carbon dioxide, ammonia, methane.
- Noble Gases (e.g. Neon, Helium) exist as single atoms because they have a full valence shell.
- Noble gases are stable and unreactive.
- Most atoms undergo chemical bonding to achieve the noble gas configuration in thir outermost shell.
- They do so by losing/gaining or sharing their valence electrons.
- Atom: Smallest particle of an element.
- Molecule: Two or more atoms chemically combined together.
- Ions: Atoms with an overall charge (after losing or gaining electrons)
- Formula unit: Show how ions in an ionic compound are electro-statically bonded together.
- Between metals and non-metals.
- Metal atom loses its valence electrons.
- These electrons are passed to the non-metal atom.
- The positive and negative charge on the two sets of ions electro-statically attract each other and form an ionic bond.
- E.g.: Sodium Chloride. Na loses 1 electron. Na now has 11 protons but 10 electrons. Overall charge of ion = (+). Metals form positively charged ions. The electron from Na is passed on to Cl. Cl now has 17 protons but 18 electrons. Overall charge on ion = (-). Non-metals form negatively charged ions.
- Covalent bonds are formed when non-metals react with one another
- Non-metals bond by sharing their valence electrons
- After bonding, each atom has an electronic configuration of a noble gas( duplet or octet stracture)
- A molecule is a group of two or more atoms held together by covalent bonds
- Place positive (metal) ion in one bracket, negative (non-metal) ion in another.
- Both ions should have complete valance shells.
- The negative ion should possess an electron from the meal atom.
- Show the charges on each ion.
- Show the numbers of each ion if there are more than one.
To determine the chemical formula of ionic compounds: All positive charges must be equal to the negative charges.
- e.g. Ca2+ and Cl-
- There needs to be two chloride ions to balance out the two positive charges.
- Therefore the chemical formula for this ionic compound is CaCl2
- Move the numerical value of the charge on each ion diagonally to the other ion
- In the chemical formula, numbers of ions within an ionic compounf are written as subscripts.
- Between non-metals.
- Valence electrons are shared between atoms.
- Each atom in the molecule should have a complete valence shell
- Shared electrons within overlapping area between atoms.
- Valency of atom is usually equal to the number of covalent bonds it can form ( e.g. Cl can form 1 bond, O can form 2)
4) Valency and Formula
- Valency is the combining power of an atom
- In ionic bonding valency of atoms is usually equal to the charges of the ions formed.
- The total combining power of the component elements of the compound must be the same.
- The chemical formula of a compund states the number and types of atoms in each compound.
- There are two ways to describe the number and types of atoms in a molecule of a compound. e.g. Water.
- Using chemical formula: H2O
- Using words: Each water molecule contains two atoms of hydrogen and one atom of oxygen combined together.
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